Hard Anodize
[MIL-A-8625F]
Type III, Class 1 & 2Hard anodizing is a
term used to describe anodic coatings with surface hardness and/or abrasion resistance as
their primary characteristic.
These anodic coatings are usually thick, greater than .001" (50% buildup and 50%
penetration), by normal anodizing standards, and they are produced using special anodizing
conditions. Thick coatings (over .0004") will tend to break down sharp edges. Alloys
with a very high copper or silicon content are less suitable for this process.
The color of the natural anodic coating depends on the alloy and the coating
thickness, e.g. 6061 has a tan or gray color which darkens to almost black at .003",
6063 has an amber shade which darkens to bronze. Both are considered clear.
After hard anodizing surfaces may be sealed in boiling
distilled water, sodium dichromate solution, dewatering oil, wax or PTFE solutions.
Dichromate sealing improves the fatigue properties, but
decreases the abrasion resistance to some extent (in common with other aqueous sealing
solutions). For this reason, aqueous sealing processes are not normally used where high
wear resistance is required. Hard anodized coatings may be impregnated with oils,
silicones or dry lubricants for improvement of anti-friction properties during this
sealing procedure. Corrosion resistance could be improved by PTFE impregnation.
For best resistance to wear and abrasion it is preferable to use pure aluminum or
alloys with the lower values or alloying additions.
Hard anodized aluminum shows a good heat resistance, and the coatings also give
very good electrical insulation. This property can be further improved by hot water
sealing and waxing.
Abrasion resistance for unsealed coatings are tested by
method 6192 of FED-STD-141 using CS-17 wheels with 1000gm load.
The anodic coating shall have a maximum wear index of 3.5mg/1000 cycles on aluminum
alloys having a copper content of 2 percent or higher. The wear index for all alloys shall
not exceed 1.5mg/1000 cycles.
Type III: Thickness as specified on drawing. If not specified
nominal thickness shall be 0.002" (+/ - .0002).
Class 1: Not dyed or pigmented.
Class 2: Dyed. (Specify color on contract). Hard anodic
oxide coatings find application in the engineering industry for components which require
very wear resistant surfaces. "Flash" hard anodize may be used instead of
conventional anodize for corrosion resistance. |